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HOME/JOURNAL/techniques
techniques•January 8, 2025•8 min READ

Emulsion Mastery: The Physics of Mayonnaise, Hollandaise, and Beyond

Understand the molecular science behind stable emulsions and how precision technique prevents breaking.

DJP
Dr. James Park
Contributing Writer
Emulsion Mastery: The Physics of Mayonnaise, Hollandaise, and Beyond

Emulsions represent a triumph of technique over thermodynamics. Oil and water naturally separate, but proper emulsification creates stable suspensions that form the foundation of countless sauces.

Temperature control is critical. For mayonnaise, all ingredients should be at 20°C (68°F). Cold eggs won't emulsify properly, while warm ingredients risk bacterial growth. Use a precision thermometer to verify temperatures before beginning.

The addition rate determines success. Begin with 5ml oil per 30 seconds of whisking, gradually increasing as the emulsion stabilizes. Too rapid addition overwhelms the emulsifier's capacity, causing the mixture to break. Our precision scales enable exact measurement of addition rates.

Lecithin in egg yolk acts as an emulsifier, with hydrophilic heads attracted to water and hydrophobic tails to oil. This molecular structure creates a stable interface between the two phases. Understanding this mechanism explains why adding more yolk can rescue a broken emulsion.

For hollandaise, maintain butter temperature at 45-50°C. Below this range, butter solidifies; above it, proteins denature and the emulsion breaks. Precise temperature control, measured with an instant-read thermometer, ensures consistent results.

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